I have the same problem. I need to open the captcha solver in Firefox but jDownloader keeps trying but failing to open it in Chrome, which is the default browser on my computer. Following the solution provided by Jiaz, I changed the url in the Settings/Advanced Settings/GeneralSettings.browsercommandline section to [ "C:\\Program Files (x86)\\Mozilla Firefox\\firefox.exe", "%s" ]. But even then jDownloader keeps opening the captcha solver in Chrome. I don't understand why this happens.
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